Surfactants - Anionic Available — Bulk Only

Sulfamic Acid (Sulphamic Acid, Amidosulfonic Acid)

CAS 5329-14-6 · Formula H3NO3S · MW 97.10 g/mol

A dry crystalline strong acid used for descaling, metal cleaning, and chlorine stabilization in industrial water systems. it is used for acid cleaning and descaling of metals, in electroplating, pulp and paper bleaching, and as a chlorine stabilizer in swimming pools, cooling towers, and paper mills, as well as a primary standard in acid-base titrimetry.

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UN Number
UN 2967
Hazard Class
Class 8
HS Code
2811.19
At a Glance
Material Family
Surfactants - Anionic
Record Type
Pure compound
Primary Role
Cleaning / Degreasing · Wetting
Applications & Use Cases
  • Descaling and cleaning: Removes scale and rust in metal and equipment cleaning.
  • Chlorine stabilizer: Stabilizes chlorine in pools, cooling towers, and paper mills.
  • Electroplating: Acid component in plating and metal-finishing baths.
  • Pulp and paper: Bleaching agent in pulp and paper processing.
  • Analytical standard: Primary standard for alkalimetric titration.
Physical Properties
Melting Point
Melting point equals 205 °C
Boiling Point
DECOMP @ BOILING POINT
Density
2.15
Solubility
SPARINGLY SOL IN ALC, METHANOL; SLIGHTLY SOL IN ACETONE; INSOL IN ETHER; FREELY SOL IN NITROGENOUS BASES AND IN NITROGEN CONTAINING ORG SOLVENTS
pH
1N, pH=0.41; 0.75N, pH=0.5; 0.5N, pH=0.63; 0.25N, pH=0.87; 0.1N, pH=1.18; 0.05N, pH=1.41; 0.01N, pH=2.02
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

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DOT / UN Transport Classification
DOT hazard class 8 placard
UN / DOT NumberUN 2967
Hazard Class / DivisionClass 8
Packing GroupIII
Proper Shipping NameSulfamic acid

Transport classification per the UN Model Regulations / 49 CFR 172.101 Hazardous Materials Table. Confirm against the grade-specific SDS (Section 14) before shipping.

HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2811 . 19
Chapter 28
Inorganic chemicals; compounds of precious metals and rare-earth metals
Heading 28.11
Internationally harmonized (WCO HS)
Subheading 2811.19
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
5329-14-6
Molecular Formula
H3NO3S
Molecular Weight
97.10 g/mol
IUPAC Name
sulfamic acid
PubChem CID
InChI Key
IIACRCGMVDHOTQ-UHFFFAOYSA-N
Synonyms & Trade Names
SULFAMIC ACID Amidosulfonic acid Sulphamic acid Amidosulfuric acid Aminosulfonic acid Sulfamidic acid Sulfaminic acid Imidosulfonic acid Jumbo Aminosulfuric acid Kyselina sulfaminova Kyselina amidosulfonova
Full Description

Sulfamic acid (sulphamic acid, amidosulfonic acid; NH2SO3H, CAS 5329-14-6) is a dry, non-volatile, moderately strong solid acid — a white, odorless crystalline powder that dissolves in water to a strongly acidic solution without the choking fumes of hydrochloric acid. That combination makes it the descaling and cleaning acid of choice for boilers, heat exchangers and cooling systems, and a sulfonating agent and intermediate in chemical synthesis. Identity: PubChem.

What is sulfamic acid?

Sulfamic acid is a solid mineral acid, NH2SO3H. Unlike liquid mineral acids it ships and meters as a stable, non-hygroscopic crystal, yet in solution it is a strong acid comparable to the first proton of sulfuric acid. It is non-volatile and essentially fume-free, descales without etching as aggressively as HCl on many metals, and forms water-soluble salts (sulfamates) with scale-forming metals — the reasons it dominates closed-system descaling.

Applications by sector

Industrial & institutional cleaning. Descaling of boilers, heat exchangers, condensers, cooling towers and CIP circuits; removal of limescale, rust, beerstone, milkstone and cement/grout haze; a common active in acidic cleaners and toilet/hard-surface descalers. Metal finishing. Pickling and surface preparation where a controllable, low-fume acid is preferred. Sulfonation & synthesis. A sulfonating/amidosulfonating reagent and intermediate for sulfamates, dyes, sweeteners (cyclamates) and herbicides (ammonium sulfamate). Pulp, paper & textile. Chlorine/anti-chlor control and bleaching. Water treatment. Chloramine and scale control. Match grade and concentration to the duty.

Forms and grades

Sulfamic acid is supplied as a white crystalline powder or granule, in technical and higher-purity grades. Specify assay, particle size and any purity requirement on the RFQ; the CoA documents the lot.

Handling and documentation

Sulfamic acid is an acidic irritant — harmful to skin and eyes in solution. Do not mix it with chlorine bleach, hypochlorite or nitrites, which can release hazardous gases. Handle per the current Safety Data Sheet (SDS); each lot ships with a Certificate of Analysis (CoA).

Bulk supply and RFQ

RawSource stocks and supplies sulfamic acid in bulk — bags, super sacks and bulk — from domestic US stock to cleaning, water-treatment, metal-finishing and chemical-synthesis buyers, with CoA and SDS per lot. Submit an RFQ with your grade and target quantity for a current quote. Related metal-treatment and descaling chemistries: hydrofluoric acid, ammonium bifluoride, phosphoric acid, oxalic acid, sulfamic acid.

Typical Properties

Typical reference values, not a specification; the Certificate of Analysis (CoA) for the lot governs.

Property Typical Value
Chemical Name Sulfamic acid (sulphamic acid, amidosulfonic acid)
CAS Number 5329-14-6
Molecular Formula NH2SO3H (H3NO3S)
Molecular Weight ~97.1 g/mol
Appearance White, odorless crystalline powder/granule
Solubility Soluble in water (strongly acidic, non-fuming)
Character Dry, non-volatile, moderately strong solid acid
Incompatibilities / handling Do not mix with chlorine/hypochlorite/nitrites; refer to the current SDS

Frequently Asked Questions

What is sulfamic acid used for?

Sulfamic acid (CAS 5329-14-6) is used as a descaling and cleaning acid for boilers, heat exchangers, cooling towers and CIP systems (limescale, rust, beerstone, cement haze), as a metal-pickling acid, and as a sulfonating agent and intermediate for sulfamates, dyes, sweeteners and herbicides.

Why use sulfamic acid instead of hydrochloric acid for descaling?

Sulfamic acid is a solid, so it ships and meters more conveniently and is essentially fume-free, and it is less aggressive toward many metals than HCl while still dissolving scale effectively. It is the common choice for closed cooling and boiler systems. It is still an acid — handle per the SDS.

Is sulfamic acid safe to handle?

It is an acidic irritant that is harmful to skin and eyes in solution, and it must never be mixed with chlorine bleach, hypochlorite or nitrites (which can release hazardous gases). Handle it with appropriate PPE per the current SDS; “lower-fuming than HCl” does not mean hazard-free.

What is the formula and CAS of sulfamic acid?

Sulfamic acid is NH2SO3H (H3NO3S), CAS 5329-14-6 (PubChem CID 5987), ~97.1 g/mol. The CoA documents assay and grade.

How is bulk sulfamic acid supplied and quoted?

RawSource supplies it as a crystalline powder/granule in bags, super sacks and bulk from domestic US stock, with CoA and SDS per lot. Pricing is quote-based on grade and volume; submit an RFQ with your target quantity and ship-to.

Disclaimer. Information on this page — including chemical properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot you purchase governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim, or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information.

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.