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Oxalic Acid (Ethanedioic Acid)

CAS 144-62-7 · Formula C2H2O4 · MW 90.03 g/mol

A strong dicarboxylic acid used across metal cleaning, textile processing, bleaching and rare-earth refining. Established uses include metal cleaning and rust/stain removal, textile finishing, stripping and bleaching, leather and straw bleaching, calico printing and dyeing, manufacture of oxalate salts and dyes, rare-earth processing, and service as a chelating and analytical reagent.

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UN Number
UN 3261
Hazard Class
Class 8
HS Code
2917.11
At a Glance
Material Family
Acids & Salts
Record Type
Pure compound
Primary Role
Chelation / Sequestration · pH Adjustment
Solubility
50 to 100 mg/mL at 24 °C
Functional Roles
OXALIC ACID
CHELATING
Industries Served
Applications & Use Cases
  • Metal cleaning: rust, scale and stain removal from metal surfaces
  • Textile processing: stripping, finishing and bleaching of textiles
  • Bleaching: bleaching of leather, straw and wood
  • Chemical manufacture: feedstock for oxalate salts and dyes
  • Rare-earth processing: precipitation and processing reagent in metal refining
Physical Properties
Melting Point
189 °C (Decomposes)
Boiling Point
Sublimes
Density
1.9 at 15 °C
Solubility
50 to 100 mg/mL at 24 °C
Vapor Pressure
0.001 mmHg at 20 °C
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

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DOT / UN Transport Classification
DOT hazard class 8 placard
UN / DOT NumberUN 3261
Hazard Class / DivisionClass 8
Proper Shipping NameCorrosive solid, acidic, organic, n.o.s

Transport classification per the UN Model Regulations / 49 CFR 172.101 Hazardous Materials Table. Confirm against the grade-specific SDS (Section 14) before shipping.

HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2917 . 11
Chapter 29
Organic chemicals
Heading 29.17
Internationally harmonized (WCO HS)
Subheading 2917.11
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
144-62-7
Molecular Formula
C2H2O4
Molecular Weight
90.03 g/mol
IUPAC Name
oxalic acid
INCI Name
OXALIC ACID
PubChem CID
InChI Key
MUBZPKHOEPUJKR-UHFFFAOYSA-N
Synonyms & Trade Names
oxalic acid ethanedioic acid Aktisal Aquisal Oxiric acid Oxaalzuur Oxalsaeure Kyselina stavelova Acidum oxalicum Acide oxalique Acido ossalico Ethanedionic acid NCI-C55209 Ethane-1,2-dioic acid Oxalic acid, anhydrous
Full Description

Oxalic acid (ethanedioic acid; C2H2O4, CAS 144-62-7; usually supplied as the dihydrate, CAS 6153-56-6) is the simplest dicarboxylic acid and one of the strongest organic acids. It is a white crystalline solid that acts as a reducing agent, a metal chelator and a bleaching/cleaning acid. Those properties make it a workhorse for rust and stain removal, wood bleaching, metal finishing and anodizing, and minerals and rare-earth processing. Identity: PubChem.

What is oxalic acid?

Oxalic acid is HOOC–COOH, two carboxyl groups back-to-back. That structure makes it a comparatively strong organic acid, an effective reducing agent, and a chelator that binds iron and calcium — which is why it both dissolves rust/iron stains and precipitates metals. It is normally handled as the crystalline dihydrate; an anhydrous grade is also available. It is a toxic material and is treated accordingly.

Applications by sector

Cleaning & restoration. Rust, iron-stain and tannin removal; wood bleaching and deck brightening; marble, stone and masonry cleaning; radiator and equipment cleaning. Metal finishing. The electrolyte in oxalic-acid anodizing, plus pickling, electropolishing and metal cleaning. Minerals & rare earths. Leaching and the precipitation of rare-earth and other metal oxalates in extraction and refining. Textile & leather. Bleaching and as a mordant/redox agent. Synthesis. A reducing agent and chemical intermediate. Match grade and concentration to the duty.

Forms and grades

Oxalic acid is supplied as the crystalline dihydrate (the common commercial form) and as an anhydrous grade, in technical and higher-purity grades. Specify form, assay and particle size on the RFQ; the CoA documents the lot.

Handling and documentation

Oxalic acid is toxic and corrosive — harmful or fatal if swallowed and an irritant/corrosive to skin and eyes. Handle with appropriate PPE per the current Safety Data Sheet (SDS); each lot ships with a Certificate of Analysis (CoA). Hazard and exposure data come from the SDS.

Bulk supply and RFQ

RawSource stocks and supplies oxalic acid in bulk — bags, super sacks and bulk — from domestic US stock to cleaning/restoration, metal-finishing, minerals and textile buyers, with CoA and SDS per lot. Submit an RFQ with your form (dihydrate/anhydrous), grade and target quantity. Related metal-treatment and descaling chemistries: hydrofluoric acid, ammonium bifluoride, phosphoric acid, oxalic acid, sulfamic acid.

Typical Properties

Typical reference values, not a specification; the Certificate of Analysis (CoA) for the lot governs.

Property Typical Value
Chemical Name Oxalic acid (ethanedioic acid)
CAS Number 144-62-7 (anhydrous); 6153-56-6 (dihydrate)
Molecular Formula C2H2O4 (anhydrous)
Molecular Weight ~90.0 g/mol (anhydrous)
Appearance White crystalline solid (commonly the dihydrate)
Solubility Soluble in water
Character Strong dicarboxylic organic acid; reducing agent and metal chelator
Hazard / handling Toxic and corrosive — refer to the current SDS

Frequently Asked Questions

What is oxalic acid used for?

Oxalic acid (CAS 144-62-7) is used for rust and iron-stain removal, wood bleaching and stone/masonry cleaning, as the electrolyte in oxalic-acid anodizing and in metal finishing, and in minerals and rare-earth processing as a leaching and oxalate-precipitation agent.

Is oxalic acid the dihydrate or anhydrous?

Both grades exist; the crystalline dihydrate (CAS 6153-56-6) is the common commercial form, and an anhydrous grade (CAS 144-62-7) is also available. Specify which you need, since the water of crystallization affects dosing.

Is oxalic acid dangerous?

Yes. Oxalic acid is toxic and corrosive — harmful or fatal if swallowed and an irritant/corrosive to skin and eyes. Handle it with appropriate PPE per the current SDS.

What is the formula and CAS of oxalic acid?

Oxalic acid is C2H2O4, CAS 144-62-7 anhydrous (PubChem CID 971) or 6153-56-6 as the dihydrate, ~90.0 g/mol anhydrous. The CoA documents form, assay and grade.

How is bulk oxalic acid supplied and quoted?

RawSource supplies it as dihydrate or anhydrous crystal in bags, super sacks and bulk from domestic US stock, with CoA and SDS per lot. Pricing is quote-based on form, grade and volume; submit an RFQ with your target quantity.

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.