Glycols & Polyols Available — Bulk Only

Pentaerythritol

Penta
CAS 115-77-5 · Formula C5H12O4 · MW 136.15 g/mol

A white crystalline tetraol used to manufacture alkyd resins, synthetic ester lubricants, PVC stabilizers, and intumescent flame-retardant systems.

Request SDS
HS Code
2905.42
At a Glance
Material Family
Glycols & Polyols
Record Type
Pure compound
Primary Role
Crosslinking / Curing · Synthesis Intermediate
Solubility
Soluble in ethanol, glycerol, ethylene glycol, formamide. Insoluble in acetone, benzene, paraffin, ether, carbon tetrachloride
Functional Roles
PENTAERYTHRITOL
HUMECTANTSKIN CONDITIONING
Applications & Use Cases
  • Alkyd resins: Polyol for alkyd resin and varnish manufacture.
  • Rosin/tall-oil esters: Esterification polyol for rosin ester resins.
  • Radiation-cure monomers: Backbone for acrylate monomers (e.g., PETA).
  • Synthetic lubricants: Feedstock for synthetic ester base stocks.
  • Antioxidants: Intermediate for hindered-phenol antioxidants.
Physical Properties
Physical Description
Colorless to white, crystalline, odorless powder
Appearance
Colorless to white, crystalline powder
Odor
Odorless
Boiling Point
Sublimes
Melting Point
261 °C
Flash Point
About 240 °C (open cup)
Solubility
Soluble in ethanol, glycerol, ethylene glycol, formamide. Insoluble in acetone, benzene, paraffin, ether, carbon tetrachloride
Density
1.39 at 25 °C
Vapor Density
Relative vapor density (air = 1): 4.7
Vapor Pressure
Vapor pressure, Pa at 20 °C: 0.013
LogP
log Kow = -1.69
Autoignition Temperature
450 °C
Heat Of Combustion
-8.730 BTU/LB= -4.850 CAL/G= -203X10+5 J/KG
Refractive Index
Index of refraction: 1.548 at 25 °C/D
Dissociation Constants
pKa = 14.10
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

Request SDS →
HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2905 . 42
Chapter 29
Organic chemicals
Heading 29.05
Internationally harmonized (WCO HS)
Subheading 2905.42
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
115-77-5
Molecular Formula
C5H12O4
Molecular Weight
136.15 g/mol
IUPAC Name
2,2-bis(hydroxymethyl)propane-1,3-diol
INCI Name
PENTAERYTHRITOL
PubChem CID
InChI Key
WXZMFSXDPGVJKK-UHFFFAOYSA-N
Synonyms & Trade Names
PENTAERYTHRITOL 2,2-bis(hydroxymethyl)propane-1,3-diol Pentek Tetramethylolmethane Auxinutril Maxinutril Monopentek Pentaerythrite Penetek Metab-Auxil Monopentaerythritol Hercules P6 Tetrakis(hydroxymethyl)methane 2,2-Bis(hydroxymethyl)-1,3-propanediol Methane tetramethylol pentaerithrityl Tetrahydroxymethylmethane 1,3-Propanediol, 2,2-bis(hydroxymethyl)- Auxitrans THME
Full Description

Pentaerythritol is a high-functionality tetraol — a four-hydroxyl building block for alkyd and ester resins, synthetic lubricants, PVC stabilizers and intumescent flame retardants. Identity: CAS 115-77-5.

What it is

Pentaerythritol (CAS 115-77-5, C5H12O4) is a white crystalline tetrahydric alcohol. Its four primary hydroxyl groups make it a versatile, high-functionality polyol and esterification building block.

Industrial uses

It is used to make alkyd resins for coatings (raising crosslink density and hardness), rosin and fatty-acid esters (tackifiers, gum esters), synthetic ester lubricants (POE), PVC co-stabilizers, and as the carbon/char source in halogen-free intumescent flame-retardant systems. It is also a building block for stabilizers and specialty esters.

It is the carbon source in intumescent systems — see APP and the flame retardants guide.

Forms, grades and handling

Pentaerythritol is supplied as mono- and technical/di-grades (powder/crystalline) in bags and bulk; specify grade. Properties are typical reference values; the Certificate of Analysis (CoA) for the lot you buy governs. Always consult the current Safety Data Sheet (SDS) before handling, and confirm regulatory status and suitability for your application and jurisdiction. Each lot ships with CoA, TDS and SDS.

Bulk supply and RFQ

RawSource sources Pentaerythritol direct from producers in bulk, with CoA, TDS and SDS per lot. Tell us the grade, particle size or specification and quantity you need, and we will quote it. Products are sold for industrial and professional use.

Typical Properties

Typical reference values, not a specification; the Certificate of Analysis (CoA) for the lot governs.

Property Typical Value
Chemical / class Polyhydric alcohol (tetraol)
CAS Number 115-77-5
Molecular Formula C5H12O4
Molecular Weight 136.15 g/mol
Handling Refer to the current SDS

Regulatory & registration requirements

  • TSCA (US):
  • REACH (EU):
  • EC number: 204-104-9

Source: EPA TSCA Inventory (July 2025 release) · ECHA CHEM — retrieved 2026-07-12

Solutions Using This Product

Process-solution guides on this site that specify this chemistry:

Frequently Asked Questions

What is pentaerythritol used for?

Pentaerythritol (CAS 115-77-5) is a tetraol used to make alkyd resins, rosin and fatty-acid esters, synthetic ester lubricants, PVC co-stabilizers, and as the carbon/char source in intumescent flame retardants. RawSource supplies it for industrial use.

What grade of pentaerythritol should I use?

Mono-pentaerythritol (high mono content) is used where high purity/functionality is needed (e.g. POE lubricants, premium alkyds); technical/di-grades suit general resin and ester use. Specify the application and we will quote the grade.

How is bulk pentaerythritol supplied and quoted?

RawSource supplies pentaerythritol in bulk with CoA, TDS and SDS per lot. Pricing is quote-based on grade, particle size/specification and volume; submit an RFQ with your application and quantity.

What is the REACH and TSCA regulatory status of Pentaerythritol?

Pentaerythritol (CAS 115-77-5) is subject to U.S. TSCA Inventory requirements; supplying it into the EU requires valid REACH registration ((EC) No 1907/2006). RawSource cannot verify a third-party supplier's registrations — buyers should require documented TSCA and REACH compliance for their jurisdiction and volume (EC 204-104-9).

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.