Mineral Fillers & Pigments Available — Bulk Only

Antimony Trioxide (Antimony(III) Oxide, ATO)

Sb2O3
CAS 1309-64-4 · Formula O3Sb2 · MW 291.52 g/mol

A flame-retardant synergist and polyester catalyst with opacifying and pigment functions. It is used as a flame-retardant synergist in plastics and textiles, a plastics stabilizer, a polycondensation catalyst (including for PET), an opacifier in glass, ceramics, and enamels, and a pigment.

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HS Code
2825.80
At a Glance
Material Family
Mineral Fillers & Pigments
Record Type
Pure compound
Primary Role
Flame Retardancy
Functional Roles
Applications & Use Cases
  • Flame-retardant synergist: synergist with halogenated systems in plastics and textiles
  • Polyester catalyst: polycondensation catalyst for PET
  • Opacifier: glass, ceramic, and enamel opacification
  • Stabilizer / pigment: plastics stabilizer and pigment
Physical Properties
Melting Point
655 °C
Boiling Point
1550 °C at 760 mmHg (sublimes); 870 °C at 210 mmHg
Density
5.2 at 25 °C
Solubility
< 1 mg/mL at 20 °C
Vapor Pressure
1 mmHg at 574 °C
Flash Point
Not Applicable. Not flammable
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

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HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2825 . 80
Chapter 28
Inorganic chemicals; compounds of precious metals and rare-earth metals
Heading 28.25
Internationally harmonized (WCO HS)
Subheading 2825.80
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
1309-64-4
Molecular Formula
O3Sb2
Molecular Weight
291.52 g/mol
IUPAC Name
bis(antimony(3+));tris(oxygen(2-))
PubChem CID
InChI Key
GHPGOEFPKIHBNM-UHFFFAOYSA-N
Synonyms & Trade Names
Diantimony trioxide ANTIMONY TRIOXIDE Antimonious oxide Antimony sesquioxide Exitelite Timonox Twinkling star Antimony White Thermoguard B Thermoguard L Thermoguard S White star Fireshield H Dechlorane A-O Stibiox MS Amspec-KR Patox C Patox H Patox L Patox M
Full Description

Antimony trioxide (ATO) is the classic flame-retardant synergist — it has little effect on its own but sharply boosts the efficiency of halogenated flame retardants, letting formulators use less of them. It is used together with a halogen source, not as a halogen-free solution. Identity: CAS 1309-64-4.

What it is

Antimony trioxide (CAS 1309-64-4, Sb2O3) is a white powder. In flame retardancy it is a synergist for brominated and chlorinated systems; it is also used as a catalyst (e.g. in PET) and as a pigment/opacifier. Confirm regulatory status for your market and end use.

How it performs in fire

It works in the gas phase: with a halogen source it forms antimony halides and oxyhalides that scavenge the radicals feeding the flame, multiplying the effectiveness of the halogenated flame retardant so a lower total loading reaches the fire rating. Alone it does little, so it is always paired with a halogen donor.

Applications

ATO is used as a synergist in halogenated flame-retardant plastics, PVC, textiles, rubber and coatings, dosed with a brominated or chlorinated flame retardant. For halogen-free routes, see the mineral and intumescent options in the flame retardants guide; zinc borate is used as a partial antimony replacement.

Forms, grades and handling

ATO is supplied as a white powder in a range of particle sizes in bags and bulk. Properties are typical reference values; the Certificate of Analysis (CoA) for the lot you buy governs. Handle per the current Safety Data Sheet (SDS), and confirm regulatory status and restrictions for your market and end use. Each lot ships with CoA, TDS and SDS.

Bulk supply and RFQ

RawSource sources Antimony Trioxide direct from producers in bulk, with CoA, TDS and SDS per lot. Tell us your polymer or system, the fire test you must pass, your maximum loading, and any particle-size or grade requirement, and we will quote the right grade. See the full range and selection logic in the flame retardants guide.

Typical Properties

Typical reference values, not a specification; the Certificate of Analysis (CoA) for the lot governs.

Property Typical Value
Chemical / class Flame-retardant synergist (antimony oxide)
Flame-retardant type Gas-phase synergist
Role in fire performance Boosts halogenated flame retardants
CAS Number 1309-64-4
Molecular Formula Sb2O3
Molecular Weight 291.5 g/mol
Handling Refer to the current SDS

Frequently Asked Questions

What is antimony trioxide used for in flame retardancy?

Antimony trioxide (ATO, CAS 1309-64-4) is a gas-phase synergist that greatly boosts halogenated flame retardants, so less total flame retardant is needed to reach a fire rating. It is used with a brominated or chlorinated flame retardant, not as a standalone or halogen-free solution. It is also used as a PET catalyst and pigment.

Is antimony trioxide halogen-free?

No — antimony trioxide is a synergist that only works together with a halogen source, so it is part of halogenated systems. For halogen-free flame retardancy use mineral hydroxides, intumescent or nitrogen systems.

Can zinc borate replace antimony trioxide?

Zinc borate is often used as a partial replacement for or synergist with antimony trioxide, reducing antimony use while adding smoke and afterglow suppression; the right ratio depends on the system.

How is bulk antimony trioxide supplied and quoted?

RawSource supplies antimony trioxide in bulk with CoA, TDS and SDS per lot. Pricing is quote-based on grade, particle size and volume; submit an RFQ with your polymer/system and the fire test you must pass.

Disclaimer. Information on this page — including chemical properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot you purchase governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim, or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information.

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.