Food & Beverage / Solution Family

Glycols & Polyols

Humectant glycols and polyols u2014 vegetable glycerin, propylene glycol, mannitol and lactitol u2014 plus glyceryl-ester emulsifiers for moisture control, water-activity reduction, and emulsification in food and beverage systems.

Overview

Glycols and polyols are polyhydric alcohols that bind water through multiplenhydroxyl groups. In food and beverage formulation they do two jobs: humectantsnsuch as glycerin and propylene glycol lower water activity to control texture and shelfnstability, and bulk polyols such as mannitol and lactitol add sugar-free body andncrystallization control. Glyceryl-ester emulsifiers sit in the same family and stabilizenoil-and-water systems. Match the grade to the application; humectant and emulsifier rolesnare not interchangeable.

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Glycerin (glycerol) is the workhorse humectant: it binds water strongly and is widelynused in bars, fondants and baked goods. The trade-off is honest u2014 glycerin contributesnsweetness and viscosity, so where a neutral carrier is wanted, propylene glycol is thenalternative for dissolving and carrying flavors and colors. Specify glycerin where moisturenretention is the priority and propylene glycol where flavor carriage and a low-sweetnessnprofile matter. Confirm permitted use levels for your jurisdiction.

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Bulk polyols give reduced-sugar texture. Mannitol has low hygroscopicity, which keepsncoatings and dustings dry, while lactitol provides bulk and mouthfeel in reduced-sugarnsystems. The glyceryl esters u2014 monostearate, monooleate, monococoate u2014 function asnemulsifiers and crumb softeners rather than humectants. For a sugar-reduced confection,npair a bulk polyol for body with a small humectant addition for moisture, and choose thenemulsifier by its required HLB and melting behavior.

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Recommended Chemistries
18 materials
Butylene Glycol (1,3-Butanediol, BG)
CAS 107-88-0
Humectant / flavor-carrier solvent Quick view
Canola Oil Glyceride and Corn Oil Blend
CAS 120962-03-0
Glyceride release / emulsifier blend Quick view
D-Mannitol (Mannitol)
CAS 69-65-8
Bulk polyol (low-hygroscopicity) Quick view
Diglycerol (Diglycerin)
CAS 627-82-7
Humectant polyol Quick view
Ethylhexylglycerin (Octoxyglycerin)
CAS 70445-33-9
Moisture Control Quick view
Glyceryl Cocoate (Glycerol Monococoate)
CAS 26402-26-6
Monoglyceride emulsifier / emollient Quick view
Glyceryl Monooleate (Glyceryl Oleate, Monoolein)
CAS 25496-72-4
Monoglyceride emulsifier Quick view
Glyceryl Monostearate SE (GMS)
CAS 123-94-4
Monoglyceride emulsifier / crumb softener Quick view
Hexylene Glycol (2-Methyl-2,4-pentanediol, HG)
CAS 107-41-5
Solvency Quick view
Lactitol
CAS 585-86-4
Bulk polyol (reduced-sugar texture) Quick view
PEG-100 Stearate
CAS 9004-99-3
Self-emulsifying emulsifier Quick view
Propylene Glycol (MPG, PG)
CAS 57-55-6
Humectant & flavor/color carrier solvent Quick view
Propylene Glycol Methyl Ether (Glycol Ether PM, PGME)
CAS 107-98-2
Solvency Quick view
Propylene Glycol Monomethyl Ether Acetate (PGMEA, PMA)
CAS 108-65-6
Solvency Quick view
Propylene Glycol Monostearate (PGMS)
CAS 1323-39-3
Emulsifier (aeration / bakery) Quick view
Propylene Glycol Monostearate, Self-Emulsifying (PGMS)
CAS 1323-39-3
Emulsifier (aeration / bakery) Quick view
Vegetable Glycerin (Glycerin, Glycerol)
CAS 56-81-5
Humectant (moisture & water-activity control) Quick view
Xylitol
CAS 87-99-0
Moisture Control Quick view
Where it's used
  • Humectancy and water-activity control in bars, fondants, fillings and soft baked goods
  • Flavor and color carriage in beverages and confections (propylene glycol, glycerin)
  • Reduced-sugar bulking and crystallization control with mannitol and lactitol
  • Crumb softening and emulsification with glyceryl-ester emulsifiers in bakery
  • Stabilizing oil-in-water emulsions in sauces, fillings and bakery systems
Frequently asked questions
What glycols and polyols does RawSource supply for food and beverage?
RawSource sources vegetable glycerin and propylene glycol (humectants), mannitol, lactitol and diglycerol (bulk polyols), and the glyceryl-ester emulsifiers glyceryl monostearate, propylene glycol monostearate, glycerol monococoate and glycerol monooleate. Industrial glycol ethers such as propylene glycol methyl ether and PMA are also stocked, but they are specified for coatings and industrial use rather than food.
What is the difference between a humectant and a bulk polyol?
A humectant such as glycerin or propylene glycol binds water to lower water activity, holding moisture and slowing spoilage. A bulk polyol such as mannitol or lactitol provides sugar-free body, texture and crystallization control. Many reduced-sugar formulations use both: a polyol for volume and a small humectant addition for moisture.
Does RawSource supply food-grade glycerin and propylene glycol in bulk?
Yes. Vegetable glycerin and propylene glycol are available in drums, totes and bulk with full SDS, TDS and COA documentation. Confirm the required food-grade or USP/FCC specification and the regulatory status for your application and jurisdiction.
Can glycerin and propylene glycol be used interchangeably?
Not directly. Glycerin is a stronger humectant and contributes sweetness and viscosity; propylene glycol is a more neutral carrier with defined use levels. Choose by whether moisture retention or low-sweetness flavor carriage is the priority.
Disclaimer. Information on this page is provided for general reference and compiled from authoritative public sources (e.g. PubChem/ECHA). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot you purchase governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim. Always consult the current Safety Data Sheet (SDS) before handling, and confirm regulatory status, classification, and suitability for your application and jurisdiction.
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