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Potassium Metabisulfite (Potassium Pyrosulfite)

CAS 16731-55-8 · Formula K2O5S2 · MW 222.33 g/mol

A solid source of sulfur dioxide used as an antioxidant, preservative, and bleaching agent in winemaking, brewing, and food. Established uses include antioxidant and preservative duty in winemaking, brewing, and the preservation of fruits and vegetables; bleaching; and use as a developing agent in photographic processing.

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UN Number
UN 1759
Hazard Class
Class 8
HS Code
2832.20
At a Glance
Material Family
Acids & Salts
Record Type
Pure compound
Primary Role
Preservation · Biocidal Action
Functional Roles
POTASSIUM METABISULFITE
HAIR WAVING OR STRAIGHTENINGPRESERVATIVEREDUCING
Applications & Use Cases
  • Winemaking & brewing: Antioxidant and antimicrobial preservative; cask and vat sanitation
  • Food preservation: Antioxidant and preservative for fruits and vegetables
  • Bleaching: Bleaching agent for straw and other materials
  • Photographic processing: Developing and antioxidant agent in film development
Physical Properties
Melting Point
Decomposes at approximately 150 °C
Density
2.3 g/cu cm
Solubility
Freely soluble in water; insoluble in alcohol
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

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DOT / UN Transport Classification
DOT hazard class 8 placard
UN / DOT NumberUN 1759
Hazard Class / DivisionClass 8
Proper Shipping NameCorrosive solids, n.o.s.

Transport classification per the UN Model Regulations / 49 CFR 172.101 Hazardous Materials Table. Confirm against the grade-specific SDS (Section 14) before shipping.

HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2832 . 20
Chapter 28
Inorganic chemicals; compounds of precious metals and rare-earth metals
Heading 28.32
Internationally harmonized (WCO HS)
Subheading 2832.20
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
16731-55-8
Molecular Formula
K2O5S2
Molecular Weight
222.33 g/mol
INCI Name
POTASSIUM METABISULFITE
PubChem CID
InChI Key
RWPGFSMJFRPDDP-UHFFFAOYSA-L
Synonyms & Trade Names
POTASSIUM METABISULFITE Potassium disulfite Dipotassium pyrosulfite Dipotassium disulfite Sobisu Dipotassium metabisulfite potassium metabisulphite Potassium disulfite (K2S2O5) Potassium pentaoxodisulfate Pyrosulfurous acid, dipotassium salt Ins-224 Potassium metabisulfite (e 224) E-224 Potassium pyrosulfite
Full Description

Potassium metabisulfite (CAS 16731-55-8) is the potassium salt of disulfurous acid, K2S2O5, and a convenient solid source of sulfur dioxide. Established uses include antioxidant and preservative duty in winemaking, brewing, and the preservation of fruits and vegetables; bleaching; and use as a developing agent in photographic processing. It also serves as a source of sulfurous acid in dyeing and engraving.

Frequently Asked Questions

What is potassium metabisulfite used for?

Potassium metabisulfite (K2S2O5, CAS 16731-55-8) is a convenient solid source of sulfur dioxide used as an antioxidant and antimicrobial preservative in winemaking and brewing, in fruit and vegetable preservation, as a bleaching agent, and as a developing/antioxidant agent in photographic processing.

What is the chemical formula for potassium metabisulfite?

Potassium metabisulfite is K2S2O5 (listed formula K2O5S2), the potassium salt of disulfurous acid, CAS 16731-55-8. This is the technical grade.

How does potassium metabisulfite release sulfur dioxide?

In contact with water or acid it liberates sulfur dioxide, which provides its antioxidant, antimicrobial, and bleaching activity. This makes it a practical dry source of SO2 and of sulfurous acid for processing applications such as dyeing and engraving.

What are the DOT shipping details for potassium metabisulfite?

Potassium metabisulfite is assigned UN 1759. Refer to the SDS for the proper shipping name, packing group, and current transport requirements; we supply the SDS with each order so you can confirm classification for your shipment.

What is the cost of bulk potassium metabisulfite?

Bulk pricing depends on grade, packaging (bags, drums, supersacks), and volume. Submit a bulk RFQ with quantity and packaging for a current quote with CoA and SDS; we do not list fixed prices.

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.