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Rheology Modifiers & Thickeners

Viscosity, suspension, and cling control for liquid cleaners u2014 salt electrolyte thickening plus xanthan gum and hydroxyethylcellulose (HEC) polymeric thickeners.

Overview

Rheology modifiers and thickeners are additives that set the viscosity,nsuspension, and flow of a cleaning product so it pours, clings, and stays homogeneous asnintended. In liquid cleaners they work two ways: electrolyte thickening,nwhere added salt builds viscosity in anionic and amphoteric surfactant systems, andnpolymeric thickening, where a biopolymer or cellulose ether builds a network thatnholds viscosity and suspends solids. Choose the mechanism by what the formula must tolerate,nnot by cost alone.

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Sodium chloride is the cheapest viscosity tool in liquid dish and hand cleaners: a smallnsalt addition thickens SLES and betaine blends along a sharp salt-response curve. Thentrade-off is real. Salt thickening collapses in high-electrolyte formulas, drifts with pH,nand gives a thin, stringy body that cannot suspend particles. Use it where the surfactantnsystem is simple and the only job is body; move to a polymer when the formula carries bleach,nbuilders, or abrasives.

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Xanthan gum and hydroxyethylcellulose (HEC) cover what salt cannot. Xanthan builds a yieldnstress that suspends abrasives, encapsulates, and pigments in cream cleansers and scouringnproducts, and it holds across a wide pH and electrolyte range. HEC is a nonionic cellulosenether that thickens surfactant systems without ionic interference and gives a smoother, lessnstringy flow. Both cost more per unit of viscosity than salt, so specify them when suspension,nelectrolyte tolerance, or cling justifies the spend.

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Where it's used
  • Building viscosity in liquid hand dishwash and all-purpose cleaners (salt response of SLES/betaine systems)
  • Suspending abrasives, encapsulates, and pigments in cream cleansers and scouring products (yield stress)
  • Cling and dwell on vertical surfaces for toilet-bowl and bathroom gels
  • Stabilizing viscosity in high-electrolyte, builder-heavy, or bleach-containing formulas where salt thickening fails
  • Controlled, pourable flow in laundry liquids and floor-care concentrates
Frequently asked questions
What thickeners are used in liquid cleaning products?
The three common tools are salt (sodium chloride), which thickens SLES- and betaine-based liquids along a salt-response curve; xanthan gum, a biopolymer that builds yield stress to suspend particles; and hydroxyethylcellulose (HEC), a nonionic cellulose ether that thickens surfactant systems with smooth flow. Salt is cheapest; the polymers add suspension and electrolyte tolerance.
When does salt thickening stop working?
Salt thickening fails when a formula already carries high electrolyte (builders, sequestrants, bleach), spans a wide pH, or must suspend solids. The salt-response curve flattens or reverses and viscosity becomes unstable. Switch to a polymeric thickener such as xanthan gum or HEC in those cases.
What is the difference between xanthan gum and hydroxyethylcellulose?
Xanthan gum builds a yield stress that suspends abrasives and particles and tolerates a wide pH and salt range, but it can give a stringy flow. HEC is nonionic and gives smoother, less stringy viscosity with good surfactant compatibility, but it suspends solids less effectively. Cream and scouring cleaners often use xanthan; clear liquids often use HEC.
Does RawSource supply rheology modifiers and thickeners in bulk?
Yes. RawSource sources sodium chloride, xanthan gum, and hydroxyethylcellulose for cleaning formulators in drums, totes, and larger bulk formats, each with CAS identification and standard documentation. Send your formula type and target viscosity for a bulk RFQ.
Disclaimer. Information on this page is provided for general reference and compiled from authoritative public sources (e.g. PubChem/ECHA). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot you purchase governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim. Always consult the current Safety Data Sheet (SDS) before handling, and confirm regulatory status, classification, and suitability for your application and jurisdiction.
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