Mineral Fillers & Pigments Available — Bulk Only

Magnesium Hydroxide (MDH)

Mg(OH)2
CAS 1309-42-8 · Formula H2MgO2 · MW 58.320 g/mol

A white mineral powder flame retardant that decomposes endothermically at higher temperatures than ATH, used in engineering plastics, wire insulation.

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HS Code
2816.10
At a Glance
Material Family
Mineral Fillers & Pigments
Record Type
Pure compound
Primary Role
pH Adjustment · Flame Retardancy
Solubility
White, friable masses or bulky, white powder; at about 700 °C is converted to MgO; sol in about 3,300 parts CO2-free water; more sol in water containing CO2; sol in dilute acids with effervescence; insol in alcohol /Magnesium carbonate hydroxide/
Functional Roles
MAGNESIUM HYDROXIDE
ABSORBENTBUFFERING
Applications & Use Cases
  • Flame retardant: Halogen-free flame retardant and smoke suppressant for polymers.
  • Acid neutralization: Neutralizing agent for acids in the chemical industry.
  • Wastewater treatment: pH adjustment and treatment in wastewater.
  • Chemical intermediate: Raw material for magnesium metal and magnesium compounds.
  • Process additive: Additive in residual fuel oil and sulfite pulp processing.
Physical Properties
Physical Description
White odorless solid; Colorless or white solid; Hygroscopic in powdered form; White odorless powder; Practically insoluble in water
Appearance
White, hexagonal crystals
Odor
Odorless
Melting Point
350 °C (decomposes)
Solubility
White, friable masses or bulky, white powder; at about 700 °C is converted to MgO; sol in about 3,300 parts CO2-free water; more sol in water containing CO2; sol in dilute acids with effervescence; insol in alcohol /Magnesium carbonate hydroxide/
Density
2.36 g/mL
pH
pH = 9.5-10.5 (aqueous slurry)
Refractive Index
Index of refraction: 1.559, 1.580
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

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HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2816 . 10
Chapter 28
Inorganic chemicals; compounds of precious metals and rare-earth metals
Heading 28.16
Internationally harmonized (WCO HS)
Subheading 2816.10
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
1309-42-8
Molecular Formula
H2MgO2
Molecular Weight
58.320 g/mol
IUPAC Name
magnesium dihydroxide
INCI Name
MAGNESIUM HYDROXIDE
PubChem CID
InChI Key
VTHJTEIRLNZDEV-UHFFFAOYSA-L
Synonyms & Trade Names
MAGNESIUM HYDROXIDE Milk of magnesia Magnesium dihydroxide Magnesium hydrate Magnesium hydroxide (Mg(OH)2) Magnesium(II) hydroxide Phillips magnesia tablets Magnesium (as hydroxide) Magnesii hydroxidum INS NO.528 Phillips milk of magnesia liquid INS-528 E-528 Hydrate, Magnesium Hydroxide, Magnesium Magmex Dulcolax Liquid MagLax Magmilax Powder
Full Description

Magnesium hydroxide (MDH) is the higher-temperature endothermic mineral flame retardant — like ATH but stable to a higher processing temperature, so it suits engineering plastics processed above ATH’s decomposition point. Identity: CAS 1309-42-8.

What it is

Magnesium hydroxide (CAS 1309-42-8, Mg(OH)2) is a white mineral powder. It is halogen-free, acts as a functional filler and smoke suppressant, and decomposes at a higher temperature than ATH.

How it performs in fire

It decomposes endothermically at roughly 300–340°C, absorbing heat and releasing water that cools and dilutes, with the residual magnesia forming a protective layer and suppressing smoke. The higher decomposition temperature lets it survive the compounding of higher-temperature polymers. Like ATH it is used at high loadings.

Applications

MDH is used in halogen-free flame-retardant polypropylene and polyamide compounds, wire and cable, and other higher-temperature polyolefin and engineering-plastic applications. For lower-temperature polymers compare aluminum hydroxide (ATH).

Forms, grades and handling

MDH is supplied as a white powder in a range of particle sizes and surface treatments in bags and bulk. Properties are typical reference values; the Certificate of Analysis (CoA) for the lot you buy governs. Handle per the current Safety Data Sheet (SDS), and confirm regulatory status and restrictions for your market and end use. Each lot ships with CoA, TDS and SDS.

Bulk supply and RFQ

RawSource sources Magnesium Hydroxide direct from producers in bulk, with CoA, TDS and SDS per lot. Tell us your polymer or system, the fire test you must pass, your maximum loading, and any particle-size or grade requirement, and we will quote the right grade. See the full range and selection logic in the flame retardants guide.

Typical Properties

Typical reference values, not a specification; the Certificate of Analysis (CoA) for the lot governs.

Property Typical Value
Chemical / class Flame retardant / smoke suppressant (mineral hydroxide)
Flame-retardant type Mineral hydroxide (endothermic)
Role in fire performance Endothermic; higher-temp; smoke suppressant
CAS Number 1309-42-8
Molecular Formula Mg(OH)2
Molecular Weight 58.3 g/mol
Handling Refer to the current SDS

Regulatory & registration requirements

  • TSCA (US):
  • REACH (EU):
  • EC number: 215-170-3

Source: EPA TSCA Inventory (July 2025 release) · ECHA CHEM — retrieved 2026-07-12

Solutions Using This Product

Process-solution guides on this site that specify this chemistry:

Frequently Asked Questions

What is magnesium hydroxide (MDH) used for?

Magnesium hydroxide (MDH, CAS 1309-42-8) is a halogen-free endothermic flame retardant for higher-temperature polymers such as flame-retardant polypropylene and polyamide compounds and wire and cable, where its ~300–340°C decomposition temperature lets it survive compounding.

Why choose MDH over ATH?

MDH decomposes at a higher temperature (~300–340°C vs ~180–200°C for ATH), so it is used for polymers processed hot enough that ATH would decompose during compounding, such as polypropylene and polyamides.

How is bulk magnesium hydroxide supplied and quoted?

RawSource supplies magnesium hydroxide in bulk with CoA, TDS and SDS per lot. Pricing is quote-based on grade, particle size and volume; submit an RFQ with your polymer/system and the fire test you must pass.

What is the REACH and TSCA regulatory status of Magnesium Hydroxide (MDH)?

Magnesium Hydroxide (MDH) (CAS 1309-42-8) is subject to U.S. TSCA Inventory requirements; supplying it into the EU requires valid REACH registration ((EC) No 1907/2006). RawSource cannot verify a third-party supplier's registrations — buyers should require documented TSCA and REACH compliance for their jurisdiction and volume (EC 215-170-3).

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.