Water Treatment / Solution Family

Inorganic Coagulants

Charge-neutralizing inorganic coagulants u2014 aluminum sulfate, ferric chloride, and polyferric sulfate u2014 for clarifying source water and wastewater and for chemical phosphorus removal.

Overview

Inorganic coagulants are metal-salt chemicals u2014 aluminum and iron(III) salts u2014nthat neutralize the negative surface charge on suspended colloids, so fine particles, color,nand phosphate collapse out of water and can be removed by settling or filtration.nIn water treatment they are the first chemical step in clarifying raw, process, and wastenstreams. Match the coagulant to source-water pH and to the contaminant you are targeting.

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The page carries three charged metal salts, with a real trade-off between cost and pHntolerance. Aluminum sulfate (alum) is the low-cost workhorse, but it works in a narrow bandnnear pH 5.5 to 7.5 and consumes alkalinity. Ferric chloride and polyferric sulfate stayneffective across a wider pH range, settle a denser floc, and strip phosphate well u2014 at higherncost and with more corrosive handling. Specify alum for routine clarification at controllednpH; specify the iron salts for cold water, color, phosphorus removal, or variable pH.

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Coagulants act in seconds and need rapid mixing; flocculation and settling follow. Jar-testnthe dose u2014 typical alum doses run tens of milligrams per liter but shift with turbidity andntemperature u2014 because overdosing depresses pH and re-stabilizes the particles you meant tondrop. Where a permit drives low total phosphorus, the iron salts at a molar Fe:P ratio set bynthe target residual are the usual route.

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Where it's used
  • Charge neutralization and clarification of municipal and industrial source water
  • Turbidity and suspended-solids removal in wastewater treatment
  • Chemical phosphorus removal to meet discharge permit limits
  • Color and dissolved-organic-carbon reduction ahead of filtration or RO
  • Sludge conditioning and primary clarification in WWTP operations
Frequently asked questions
What is the difference between a coagulant and a flocculant?
A coagulant (a charged metal salt such as alum or ferric chloride) neutralizes the charge that keeps fine particles suspended, letting them collide. A flocculant (usually a polymer) then bridges the destabilized particles into larger, settleable floc. Coagulation comes first and needs rapid mixing; flocculation follows under gentle mixing.
Should I use alum or a ferric coagulant?
Aluminum sulfate is lower cost and works well for routine clarification within roughly pH 5.5 to 7.5. Ferric chloride and polyferric sulfate tolerate a wider pH range, perform better in cold water, settle a denser floc, and remove phosphate more effectively u2014 at higher cost and with more corrosive handling. Jar-test both on your source water.
Which coagulant removes phosphorus?
Iron(III) salts (ferric chloride and polyferric sulfate) and aluminum sulfate all precipitate phosphate; the iron salts are the common choice for chemical phosphorus removal to low total-P discharge limits. Dose to a molar metal-to-phosphorus ratio set by your target residual. Confirm permit requirements for your application and jurisdiction.
Does RawSource supply water-treatment coagulants in bulk?
Yes. RawSource supplies aluminum sulfate, ferric chloride, and polyferric sulfate for coagulation and clarification in bulk u2014 drums, totes, isotanks, and tankers u2014 with SDS, TDS, and CoA. For potable-water use, specify grades certified to NSF/ANSI 60 and confirm certification for your application. Submit a spec for an RFQ.
Disclaimer. Information on this page is provided for general reference and compiled from authoritative public sources (e.g. PubChem/ECHA). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot you purchase governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim. Always consult the current Safety Data Sheet (SDS) before handling, and confirm regulatory status, classification, and suitability for your application and jurisdiction.
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