Plastics & Polymers / Solution Family

Antioxidants

Phenolic antioxidants u2014 BHT and TBHQ u2014 that protect polyolefins, styrenics, and resins from thermal and oxidative degradation during processing and service.

Overview

Polymer antioxidants are additives that interrupt the oxidation reactions thatndegrade plastics during processing and in service. They protect against the heatnand shear of compounding and against long-term thermal aging in the finished part.nHindered phenols such as BHT are the primary class for polyolefins and styrenics. Add thenantioxidant at the masterbatch or compounding stage so it is distributed through the meltnbefore the polymer sees its first heat history.

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BHT is the low-cost workhorse phenolic antioxidant: effective, widely available, and easynto disperse. The trade-off is volatility. BHT can evaporate during high-temperaturenprocessing and migrate or bloom out of thin sections over time, so the protection may notnlast the full service life of a thick or hot-running part. For durable goods, formulatorsnoften pair a primary phenol with a secondary phosphite; for short-life or cost-drivennitems, BHT on its own is adequate.

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tert-Butylhydroquinone (TBHQ) is a second hindered-phenol option, also used as anpolymerization inhibitor in monomers and unsaturated polyester resins. Choose thenantioxidant by part thickness, processing temperature, and required service life rathernthan by unit cost alone. Dose to the resin supplier's recommended range: over-additionnwastes additive and can cause plate-out, while under-addition shows up as yellowing,nembrittlement, or melt-flow drift during processing.

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Where it's used
  • Process stabilization of polyolefins during compounding and extrusion
  • Long-term thermal aging resistance in molded and extruded parts
  • Color and melt-flow retention in masterbatch production
  • Polymerization inhibition in monomers and unsaturated polyester resins
  • Oxidation protection for styrenics and engineering thermoplastics
Frequently asked questions
What antioxidants does RawSource supply for plastics?
RawSource sources the hindered-phenol antioxidants butylated hydroxytoluene (BHT) and tert-butylhydroquinone (TBHQ). BHT is the low-cost primary antioxidant for polyolefins and styrenics; TBHQ is a second phenolic option that also acts as a polymerization inhibitor in monomers and unsaturated resins.
What does a phenolic antioxidant do in a polymer?
A phenolic antioxidant interrupts the oxidation chain reactions that break polymer chains under heat and shear. It protects the melt during compounding, extrusion, and molding, and slows long-term thermal aging in the finished part, preserving color, melt flow, and mechanical properties.
Should I use a primary antioxidant alone or with a secondary stabilizer?
For short-life or cost-driven parts, a primary phenolic antioxidant such as BHT is usually adequate. For thick sections or high-temperature service, formulators often pair a primary phenol with a secondary phosphite, because the phenol consumes radicals while the phosphite decomposes peroxides. Choose by part thickness, processing temperature, and required service life.
Does RawSource supply BHT and TBHQ in bulk?
Yes. RawSource sources BHT and TBHQ in bags, drums, and bulk quantities with full documentation (CoA, TDS, SDS). Send your polymer, processing temperature, and target loading through the bulk RFQ for grade selection and pricing.
Disclaimer. Information on this page is provided for general reference and compiled from authoritative public sources (e.g. PubChem/ECHA). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot you purchase governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim. Always consult the current Safety Data Sheet (SDS) before handling, and confirm regulatory status, classification, and suitability for your application and jurisdiction.
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