Acids & Salts Available — Bulk Only

Ammonium Hydroxide (Aqueous Ammonia)

NH4OH
CAS 1336-21-6 · Formula H5NO · MW 35.046 g/mol

Aqueous ammonia for pH adjustment, cleaning, water treatment, and chemical manufacturing. It is used in the manufacture of rayon and textiles, pulp and paper, rubber, detergents and cleaners, and inks; in water purification and pH adjustment; in photographic development; and in metal extraction and refining.

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UN Number
UN 2672
Hazard Class
Class 8
HS Code
2814.20
At a Glance
Material Family
Acids & Salts
Record Type
Pure compound
Primary Role
pH Adjustment · Cleaning / Degreasing
Solubility
Exists only in solution
Functional Roles
AMMONIUM HYDROXIDE
BUFFERINGDENATURANT
Applications & Use Cases
  • pH adjustment: Alkalizer/neutralizer in process streams.
  • Cleaning & detergents: Active in industrial and household cleaners.
  • Water treatment: Purification and chloramine pH control.
  • Textiles & paper: Rayon, textile, and pulp/paper processing.
  • Metal extraction: Ammoniacal leaching and refining.
Physical Properties
Melting Point
-58 °C (25%)
Boiling Point
38 °C (25%)
Density
About 0.90 @ 25 °C/25 °C
Solubility
Exists only in solution
Vapor Pressure
2160 mm Hg @ 25 °C
pH
pH= 11.6 (1.0 N solution); 11.1 (0.1 N solution); 10.6 (0.01 N solution)
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

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DOT / UN Transport Classification
DOT hazard class 8 placard
UN / DOT NumberUN 2672
Hazard Class / DivisionClass 8
Packing GroupIII
Proper Shipping NameAmmonia solution, relative density between 0.880 and 0.957 at 15 degrees C in water, with more than 10 percent but not more than 35 percent ammonia

Transport classification per the UN Model Regulations / 49 CFR 172.101 Hazardous Materials Table. Confirm against the grade-specific SDS (Section 14) before shipping.

HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2814 . 20
Chapter 28
Inorganic chemicals; compounds of precious metals and rare-earth metals
Heading 28.14
Internationally harmonized (WCO HS)
Subheading 2814.20
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
1336-21-6
Molecular Formula
H5NO
Molecular Weight
35.046 g/mol
IUPAC Name
azanium hydroxide
INCI Name
AMMONIUM HYDROXIDE
PubChem CID
InChI Key
VHUUQVKOLVNVRT-UHFFFAOYSA-N
Synonyms & Trade Names
ammonium hydroxide Ammonia water Ammonia aqueous Aquammonia Ammonia, aqua Household ammonia Ammonia, monohydrate Ammonia water 29% Ammonium hydroxide ((NH4)(OH)) SX 1 (ammonia water) Hydroxide, Ammonium NH4OH Ammonium hydrate Ammoniumhydroxid
Full Description

Ammonium hydroxide (CAS 1336-21-6) is aqueous ammonia, supplied here at approximately 28% (Type B). It is used in the manufacture of rayon and textiles, pulp and paper, rubber, detergents and cleaners, and inks; in water purification and pH adjustment; in photographic development; and in metal extraction and refining.

Frequently Asked Questions

What is ammonium hydroxide Type B 27.9% used for?

Ammonium hydroxide (aqueous ammonia) at roughly 28% is used as an alkalizer/neutralizer for pH adjustment in process streams, as an active in industrial and household cleaners and detergents, in water purification and chloramine pH control, in rayon/textile and pulp/paper processing, and in ammoniacal metal leaching and refining. Type B denotes the approximately 27.9% concentration grade.

What is the highest concentration of ammonium hydroxide?

Aqueous ammonia is limited by ammonia solubility in water; concentrated commercial grades typically run up to about 28-30% NH3 by weight, beyond which ammonia readily off-gasses. This Type B product is supplied at approximately 27.9% maximum. Confirm the exact assay on the product Certificate of Analysis.

Is ammonium hydroxide a strong acid or a base?

Ammonium hydroxide is a weak base, not an acid; it is aqueous ammonia (NH3 in water) and raises pH, which is why it is used as an alkalizer and neutralizer. It is only partially ionized in solution, distinguishing it from strong bases like sodium hydroxide. See the SDS for handling and GHS classification.

What is the chemical identity and CAS number of ammonium hydroxide?

Ammonium hydroxide has CAS 1336-21-6 and is the aqueous solution of ammonia, classified under HS code 2814.20. This grade is supplied at approximately 27.9% NH3 (Type B). Concentration and identity are documented on the CoA.

How is bulk ammonium hydroxide shipped and packaged?

Aqueous ammonia is supplied in drums, totes, and bulk to manufacturers and ships under UN 2672 (ammonia solution). Transport requires the corresponding DOT/IMDG documentation and packaging, which we provide with the SDS and CoA. Request a bulk quote for your volume and packaging.

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.