Amines & Amides Available — Bulk Only

Diaminodiphenylmethane (MDA, 4,4′-Methylenedianiline)

CAS 101-77-9 · Formula C13H14N2 · MW 198.26 g/mol

The aromatic diamine that feeds MDI manufacture and epoxy, polyamide, and polyimide chemistry. PubChem also records its use as an epoxy and polyurethane-elastomer curing agent and as a monomer for polyamide and polyimide resins.

Safety Data Sheet
UN Number
UN 2651
Hazard Class
Class 6.1
HS Code
2921.59
At a Glance
Material Family
Amines & Amides
Record Type
Pure compound
Primary Role
Crosslinking / Curing · pH Adjustment
Industries Served
Applications & Use Cases
  • MDI precursor: Feedstock for methylene diphenyl diisocyanate and polymeric MDI.
  • Epoxy curing agent: Hardener for epoxy resins.
  • Polyurethane elastomers: Curing agent/chain extender for cast PU elastomers.
  • High-performance polymers: Monomer for polyamide and polyimide resins.
Physical Properties
Physical Description
4,4'-diaminodiphenylmethane appears as a tan flake or lump solid with a faint fishlike odor. May be toxic by inhalation or ingestion, and may be irritating to skin. Insoluble in water
Appearance
Tan flakes, lumps, or pearly leaflets from benzene
Odor
Faint, amine-like odor
Boiling Point
BP: 257 °C at 18 mm Hg; 249-253 °C at 15 mm Hg; 232 °C at 9 mm Hg
Melting Point
197 to 92 °C
Flash Point
220 °C (220 °C) (closed cup)
Solubility
Solubility (g/100mL solvent at 25 °C): 273.0 in acetone; 9.0 in benzene; 0.7 in carbon tetrachloride; 9.5 in ethyl ether; 143.0 in methanol; 0.1 in water
Density
1.15 at 25 °C
Vapor Density
6.8
Vapor Pressure
1e-07 mmHg at 25 °C (calculated)
LogP
log Kow = 1.59
Viscosity
8.3 cP at 100 °C
Heat of Vaporization
95.4 kJ/mol
pH
Weak base
Ionization Potential
10.70 eV
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

DOT / UN Transport Classification
DOT hazard class 6.1 placard
UN / DOT NumberUN 2651
Hazard Class / DivisionClass 6.1
Packing GroupIII
Proper Shipping Name4,4′-Diaminodiphenyl methane

Transport classification per the UN Model Regulations / 49 CFR 172.101 Hazardous Materials Table. Confirm against the grade-specific SDS (Section 14) before shipping.

HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2921 . 59
Chapter 29
Organic chemicals
Heading 29.21
Internationally harmonized (WCO HS)
Subheading 2921.59
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
101-77-9
Molecular Formula
C13H14N2
Molecular Weight
198.26 g/mol
IUPAC Name
4-[(4-aminophenyl)methyl]aniline
PubChem CID
InChI Key
YBRVSVVVWCFQMG-UHFFFAOYSA-N
Synonyms & Trade Names
4,4'-Methylenedianiline 4,4'-DIAMINODIPHENYLMETHANE Dadpm Methylenedianiline 4-[(4-aminophenyl)methyl]aniline Bis(4-aminophenyl)methane Dianilinemethane Dianilinomethane p,p'-Methylenedianiline Benzenamine, 4,4'-methylenebis- Epicure DDM Epikure DDM Curithane 4-(4-Aminobenzyl)aniline Jeffamine AP-20 p,p'-Diaminodiphenylmethane 4,4'-Diphenylmethanediamine Bis(p-aminophenyl)methane Sumicure M Ancamine TL
Full Description

Diaminodiphenylmethane (CAS 101-77-9), also called 4,4'-methylenedianiline, is an aromatic diamine used mainly as the precursor to methylene diphenyl diisocyanate (MDI) and polymeric MDI. PubChem also records its use as an epoxy and polyurethane-elastomer curing agent and as a monomer for polyamide and polyimide resins. Supplied as a bulk amine intermediate.

Frequently Asked Questions

What is diaminodiphenylmethane used for?

Diaminodiphenylmethane (MDA, CAS 101-77-9), also called 4,4'-methylenedianiline, is used mainly as the precursor to methylene diphenyl diisocyanate (MDI) and polymeric MDI. It also serves as an epoxy and polyurethane-elastomer curing agent and as a monomer for polyamide and polyimide resins.

What is methylenedianiline used for?

4,4'-Methylenedianiline is the same compound as MDA. Beyond being the feedstock for MDI/polymeric MDI, it is used as a hardener for epoxy resins, as a curing agent and chain extender for cast polyurethane elastomers, and as a monomer for high-performance polyamide and polyimide resins.

Is diaminodiphenylmethane the same as 4,4'-methylenedianiline?

Yes. Diaminodiphenylmethane (MDA) and 4,4'-methylenedianiline are names for the same aromatic diamine, CAS 101-77-9, formula C13H14N2. Specify by CAS when ordering to avoid synonym confusion.

How is MDA shipped and classified for transport?

For transport it is associated with UN 2651 (4,4'-diaminodiphenylmethane) and HS code 2921.59 (aromatic polyamines and derivatives: other). Consult the SDS for the full transport, GHS, and handling profile before arranging freight.

What is the cost of bulk MDA?

Bulk pricing depends on volume, packaging, and destination. Send your required quantity and ship-to details for a current quote; each shipment ships with a CoA and SDS.

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.