Acids & Salts Available — Bulk Only

Sodium Hydrosulfide (NaHS)

NaHS
CAS 16721-80-5 · Formula HNaS · MW 56.07 g/mol

A concentrated bisulfide source for leather, pulp, dye, and mineral-flotation chemistry. Used to dehair hides in leather processing, as a pulping and desulfurizing agent in pulp, paper, and rayon production, in the manufacture of sulfur dyes, and as a flotation reagent and copper depressant in ore processing.

Safety Data Sheet
UN Number
UN 2318
Hazard Class
Class 4.2
HS Code
2830.10
At a Glance
Material Family
Acids & Salts
Record Type
Pure compound
Primary Role
pH Adjustment · Synthesis Intermediate
Industries Served
Applications & Use Cases
  • Leather: Dehairing agent for hides
  • Pulp and paper: Kraft pulping and rayon desulfurizing agent
  • Dyes: Intermediate for sulfur-containing dyes
  • Mineral processing: Flotation reagent and copper depressant
  • Water treatment: Reducing agent for effluent and metals
Physical Properties
Melting Point
17 °C
Boiling Point
100 °C at 760 mmHg (approx.)
Density
1.3 at 15 °C
Solubility
SOL IN WATER, ALCOHOL, ETHER
Vapor Pressure
49.12 mmHg
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

DOT / UN Transport Classification
DOT hazard class 4.2 placard
UN / DOT NumberUN 2318
Hazard Class / DivisionClass 4.2
Packing GroupII
Proper Shipping NameSodium hydrosulfide, with less than 25 percent water of crystallization

Transport classification per the UN Model Regulations / 49 CFR 172.101 Hazardous Materials Table. Confirm against the grade-specific SDS (Section 14) before shipping.

HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2830 . 10
Chapter 28
Inorganic chemicals; compounds of precious metals and rare-earth metals
Heading 28.30
Internationally harmonized (WCO HS)
Subheading 2830.10
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
16721-80-5
Molecular Formula
HNaS
Molecular Weight
56.07 g/mol
IUPAC Name
sodium sulfanide
PubChem CID
InChI Key
HYHCSLBZRBJJCH-UHFFFAOYSA-M
Synonyms & Trade Names
SODIUM HYDROSULFIDE Sodium bisulfide Sodium sulfhydrate Sodium hydrogen sulfide Sodium mercaptan Sodium sulfide (Na(SH)) Sodium mercaptide sodium sulfanide Hydrogen sodium sulfide Sodium sulfide (Na(HS)) Sodium hydrosulfide (Na(HS)) Sodium hydrogen sulfide (NaHS) Hidrosulfuro sodics NA2922 NaHS Hydrogenosulfure de sodium
Full Description

Sodium hydrosulfide (CAS 16721-80-5, NaHS), an inorganic sulfur salt supplied as flakes or solution. Used to dehair hides in leather processing, as a pulping and desulfurizing agent in pulp, paper, and rayon production, in the manufacture of sulfur dyes, and as a flotation reagent and copper depressant in ore processing.

Frequently Asked Questions

What is sodium hydrosulfide used for?

Sodium hydrosulfide (NaHS, CAS 16721-80-5) is used to dehair hides in leather processing, as a pulping and desulfurizing agent in pulp, paper, and rayon production, as an intermediate for sulfur dyes, and as a flotation reagent and copper depressant in ore processing. It also serves as a reducing agent in effluent and metals treatment.

What is sodium hydrosulfide made from / how does it react with water?

It is an inorganic sulfur salt (formula HNaS) commonly produced by reacting hydrogen sulfide with sodium hydroxide. It is supplied as flakes or as an aqueous solution and is highly water-soluble. Consult the SDS for handling, storage, and incompatibility data before use.

Is sodium hydrosulfite a bleach? How is it different from sodium hydrosulfide?

No — these are different chemicals. Sodium hydrosulfite (dithionite) is a reducing/bleaching agent, while sodium hydrosulfide (NaHS) is a sulfur salt used in leather, pulp, dye, and mineral-processing applications. Confirm CAS 16721-80-5 when specifying sodium hydrosulfide to avoid cross-substitution.

What is the HS code and UN number for shipping sodium hydrosulfide?

The solid is classified under HS 2830.10 (sodium sulfides) and ships as UN 2318, Sodium Hydrosulfide, Solid, with less than 25% water of crystallization. Confirm the correct DOT/IMDG entry for the specific physical form (solid vs. solution) you are ordering.

How is bulk sodium hydrosulfide supplied and quoted?

It is available as flakes or as solution in drums, IBCs/totes, and bulk for industrial users. Provide your required form, concentration, and quantity to receive a bulk quote with a Certificate of Analysis and SDS.

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.