Esters Available — Bulk Only

Glycidyl Methacrylate (GMA)

CAS 106-91-2 · Formula C7H10O3 · MW 142.15 g/mol

A dual-reactive epoxy-methacrylate monomer for crosslinking and adhesion. It serves as a crosslinking and adhesion-promoting comonomer in acrylic and vinyl resins, a reactive monomer and diluent in coatings and adhesives, and an impregnant for paper and textiles.

Safety Data Sheet
UN Number
UN 2810
Hazard Class
Class 6.1
HS Code
2916.14
At a Glance
Material Family
Esters
Record Type
Pure compound
Primary Role
Crosslinking / Curing · Synthesis Intermediate
Applications & Use Cases
  • Crosslinking comonomer: Epoxy functionality in acrylic and vinyl resins.
  • Coatings and adhesives: Reactive monomer and diluent.
  • Adhesion promotion: Coupling and adhesion-promoting additive.
  • Impregnation: Treatment for paper and textiles.
Physical Properties
Physical Description
Glycidyl methacrylate is a colorless liquid with a fruity odor. Floats on water
Appearance
Colorless liquid
Odor
Fruity odor
Boiling Point
189 °C at 760 mmHg
Melting Point
freezing pt: -41.5 °C
Flash Point
84 °C (Tag open cup)
Solubility
Very soluble in benzene, ethyl ether, ethyl alcohol
Density
1.073 at 20 °C
Vapor Density
Relative vapor density (air = 1): 4.9
Vapor Pressure
Vapor pressure, kPa at 25 °C: 0.42
LogP
0.96
Viscosity
5.481 cP at 21 °C
Polymerization
METHYL METHACRYLATE, AND IN GENERAL THE METHACRYLIC ESTERS, POLYMERIZE MUCH LESS READILY THAN THE CORRESPONDING ORDINARY ACRYLATES. NONE THE LESS, THEY ARE STABILIZED BY ADDING HYDROQUINONE OR PYROGALLOL, PARTICULARLY IN THE PRESENCE OF METALLIC COPPER. /METHACRYLATES/
Refractive Index
Index of refraction: 1.448 @ 25 °C/D
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

DOT / UN Transport Classification
DOT hazard class 6.1 placard
UN / DOT NumberUN 2810
Hazard Class / DivisionClass 6.1
Proper Shipping NameToxic, liquids, organic, n.o.s.

Transport classification per the UN Model Regulations / 49 CFR 172.101 Hazardous Materials Table. Confirm against the grade-specific SDS (Section 14) before shipping.

HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2916 . 14
Chapter 29
Organic chemicals
Heading 29.16
Internationally harmonized (WCO HS)
Subheading 2916.14
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
106-91-2
Molecular Formula
C7H10O3
Molecular Weight
142.15 g/mol
IUPAC Name
oxiran-2-ylmethyl 2-methylprop-2-enoate
PubChem CID
InChI Key
VOZRXNHHFUQHIL-UHFFFAOYSA-N
Synonyms & Trade Names
GLYCIDYL METHACRYLATE 2,3-Epoxypropyl methacrylate Glycidol methacrylate SY-Monomer G Blemmer G Acriester G Blemmer GMA Light Ester G Methacrylic acid, 2,3-epoxypropyl ester 2-((Methacryloxy)methyl)oxirane 2-Propenoic acid, 2-methyl-, oxiranylmethyl ester Glycidyl alpha-methylacrylate CP 105 Glycidyl alpha-methyl acrylate 1-Propanol, 2,3-epoxy-, methacrylate SR 379 2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester monomethacrylate propylene oxide
Full Description

Glycidyl methacrylate (CAS 106-91-2), an epoxy-functional methacrylate monomer. It serves as a crosslinking and adhesion-promoting comonomer in acrylic and vinyl resins, a reactive monomer and diluent in coatings and adhesives, and an impregnant for paper and textiles.

Frequently Asked Questions

What is another name for glycidyl methacrylate?

Glycidyl methacrylate (CAS 106-91-2, C7H10O3) is also called GMA, 2,3-epoxypropyl methacrylate, and methacrylic acid 2,3-epoxypropyl ester. It is an epoxy-functional methacrylate monomer.

What is glycidyl methacrylate used for?

GMA is used as a crosslinking and adhesion-promoting comonomer that introduces epoxy functionality into acrylic and vinyl resins, as a reactive monomer/diluent in coatings and adhesives, and as an impregnant for paper and textiles.

How does glycidyl methacrylate work as a crosslinker?

The methacrylate group polymerizes into the resin backbone while the pendant epoxide remains available to react with carboxyl, amine, or hydroxyl groups, enabling post-cure crosslinking and adhesion promotion. This dual functionality is why it is used as a comonomer in acrylic/vinyl systems.

Is glycidyl methacrylate an acid or a base?

Neither; GMA is a neutral organic ester (an epoxy-functional methacrylate). Its reactivity comes from the polymerizable methacrylate double bond and the reactive epoxide ring rather than acid/base behavior.

How is glycidyl methacrylate shipped and what is its UN number?

GMA ships under UN 2810 and HS heading 2916.14 (esters of methacrylic acid); confirm current DOT classification and packaging on the SDS before transport. RawSource supplies it in bulk to manufacturers, typically stabilized with inhibitor; request a bulk quote, CoA, and SDS.

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.