Phosphate Esters & Derivatives Available — Bulk Only

2,6,7-Trioxa-1-phosphabicyclooctane-4-methanol 1-oxide (PEPA)

CAS 5301-78-0 · Formula C5H9O5P · MW 180.10 g/mol

A caged bicyclic phosphate flame retardant that forms protective char layers in halogen-free and intumescent systems for polyolefins and engineering plastics.

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CAS Number
5301-78-0
Formula
C5H9O5P
Molecular Weight
180.10 g/mol
Material Family
Phosphate Esters & Derivatives
At a Glance
Material Family
Phosphate Esters & Derivatives
Primary Role
Flame Retardancy · Synthesis Intermediate
Applications & Use Cases
  • Phosphorus-rich, char-forming intumescent flame retardant and intermediate
  • Building block for halogen-free flame retardant systems in plastics and coatings
  • Reactive component for fire-resistant textile and polymer finishes
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

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Chemical Identity
CAS Number
5301-78-0
Molecular Formula
C5H9O5P
Molecular Weight
180.10 g/mol
IUPAC Name
(1-oxo-2,6,7-trioxa-1lambda5-phosphabicyclooctan-4-yl)methanol
PubChem CID
InChI Key
YASRHLDAFCMIPB-UHFFFAOYSA-N
XLogP
-1.5
Full Description

PEPA (a caged bicyclic phosphate) is a high-phosphorus char-forming flame retardant used in halogen-free and intumescent systems for polyolefins and engineering plastics. Its rigid cage structure makes it an efficient carbonization/char source. Identity: CAS 5301-78-0.

What it is

The caged bicyclic phosphate (CAS 5301-78-0, 2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane-4-methanol 1-oxide, PEPA) is a high-melting solid with a high phosphorus content and a reactive hydroxymethyl group, so it can also be built into intumescent flame-retardant structures.

How it performs in fire

It acts in the condensed phase as a powerful char former, and its hydroxyl group lets it react into oligomeric/intumescent flame retardants. It is a building block for high-performance halogen-free FR systems.

Applications

PEPA is used as a char-forming component and intermediate in halogen-free and intumescent flame retardants for polyolefins (PP/PE) and engineering plastics, often with ammonium polyphosphate and a nitrogen source. See the flame retardants guide for intumescent systems.

Forms, grades and handling

PEPA is supplied as a high-melting white powder. Properties are typical reference values; the Certificate of Analysis (CoA) for the lot you buy governs. Handle per the current Safety Data Sheet (SDS), and confirm regulatory status and restrictions for your market and end use — flame-retardant regulation evolves. Each lot ships with CoA, TDS and SDS.

Bulk supply and RFQ

RawSource sources Caged Bicyclic Phosphate direct from producers in bulk, with CoA, TDS and SDS per lot. Tell us your polymer or system, the fire test you must pass, your maximum loading, and whether the application must be halogen-free, and we will quote the right grade. See the full range and selection logic in the flame retardants guide.

Typical Properties

Typical reference values, not a specification; the Certificate of Analysis (CoA) for the lot governs.

Property Typical Value
Chemical / class Flame retardant / char former (caged bicyclic phosphate)
Flame-retardant type Caged bicyclic phosphate (char former)
Role in fire performance Condensed-phase char (high phosphorus)
CAS Number 5301-78-0
Molecular Formula C5H9O5P
Molecular Weight 180.10 g/mol
Handling Refer to the current SDS

Frequently Asked Questions

What is the caged bicyclic phosphate PEPA used for?

PEPA (CAS 5301-78-0) is a high-phosphorus caged bicyclic phosphate used as a char-forming flame retardant and intermediate in halogen-free and intumescent systems for polyolefins and engineering plastics; its hydroxyl group lets it react into intumescent FR structures.

How is bulk the caged bicyclic phosphate (PEPA) supplied and quoted?

RawSource supplies the caged bicyclic phosphate (PEPA) in bulk with CoA, TDS and SDS per lot. Pricing is quote-based on grade and volume; submit an RFQ with your target quantity, polymer/system and the fire test you must pass.

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.