Glycols & Polyols Available — Bulk Only

Trimethylolpropane (TMP)

TMP
CAS 77-99-6 · Formula C6H14O3 · MW 134.17 g/mol

A trifunctional polyol that introduces branch points and crosslink density into resin and ester systems. Industry references record its use in alkyd resins, polyesters, urethane foams and coatings, UV-crosslinking agents and esters, and synthetic ester lubricants.

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HS Code
2905.41
At a Glance
Material Family
Glycols & Polyols
Record Type
Pure compound
Primary Role
Moisture Control · Solvency
Functional Roles
TRIMETHYLOLPROPANE
HUMECTANTSOLVENT
Applications & Use Cases
  • Alkyd and polyester resins: Triol for alkyd and polyester resin synthesis.
  • Polyurethanes: Polyol for polyurethane coatings and foams.
  • UV-curable crosslinkers: Backbone for acrylate ester crosslinkers (e.g., TMPTA).
  • Synthetic lubricants: Feedstock for synthetic ester base oils.
Physical Properties
Physical Description
Dry Powder; Liquid; Other Solid; Pellets or Large Crystals, Other Solid; Pellets or Large Crystals; Dry Powder, Liquid
Appearance
WHITE POWDER OR PLATES
Boiling Point
160 °C @ 5 MM HG
Melting Point
58 °C
Flash Point
172 °C c.c
Solubility
SOL IN ALL PROP IN WATER, ALCOHOL; INSOL IN BENZENE, CARBON TETRACHLORIDE
Density
1.084 g/cm³
Vapor Density
Relative vapor density (air = 1): 4.63
Vapor Pressure
0.0000449
LogP
-0.5
Autoignition Temperature
~375 °C
Safety & Handling
Full SDS available on request

A grade-specific Safety Data Sheet (SDS) — with the complete hazard classification, handling precautions, and transport information — is supplied with every shipment and available on request. Confirm all safety and regulatory details against the SDS for your specific grade.

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HS / Tariff Classification
Harmonized System (HS) Code — 6-digit international heading
2905 . 41
Chapter 29
Organic chemicals
Heading 29.05
Internationally harmonized (WCO HS)
Subheading 2905.41
6-digit international code — national tariff line adds further digits
Chemical Identity
CAS Number
77-99-6
Molecular Formula
C6H14O3
Molecular Weight
134.17 g/mol
IUPAC Name
2-ethyl-2-(hydroxymethyl)propane-1,3-diol
INCI Name
TRIMETHYLOLPROPANE
PubChem CID
InChI Key
ZJCCRDAZUWHFQH-UHFFFAOYSA-N
Synonyms & Trade Names
Trimethylolpropane 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol 1,1,1-TRIS(HYDROXYMETHYL)PROPANE Ethriol Hexaglycerine Etriol Ettriol TMP (alcohol) Propylidynetrimethanol 1,1,1-Trimethylolpropane Ethyltrimethylolmethane 1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)- Tri(hydroxymethyl)propane Tris(hydroxymethyl)propane 2,2-Bis(hydroxymethyl)-1-butanol Methanol, (propanetriyl)tris- 2-Ethyl-2-(hydroxymethyl)propanediol Propane, 1,1,1-tris(hydroxymethyl)-
Full Description

Trimethylolpropane (CAS 77-99-6) is a trihydric alcohol (triol) used as a branching and crosslinking polyol. Industry references record its use in alkyd resins, polyesters, urethane foams and coatings, UV-crosslinking agents and esters, and synthetic ester lubricants. Supplied as a bulk polyol intermediate.

Frequently Asked Questions

What is trimethylolpropane used for?

Trimethylolpropane (TMP, CAS 77-99-6) is a trihydric alcohol used as a branching and crosslinking polyol. It is a building block for alkyd and polyester resins, polyurethane coatings and foams, UV-curable acrylate crosslinkers such as TMPTA, and synthetic ester base oils for lubricants.

What is another name for trimethylolpropane?

TMP is also known by its IUPAC name 2-ethyl-2-(hydroxymethyl)propane-1,3-diol, and is commonly abbreviated TMP. The molecular formula is C6H14O3.

Is trimethylolpropane water soluble?

TMP is a triol (three hydroxyl groups) and is readily soluble in water, as well as in alcohols and many polar organics. This solubility profile reflects its use as a reactive polyol intermediate in resin and ester synthesis. Consult the SDS for full physical-property data.

What is the CAS number and molecular weight of trimethylolpropane?

The CAS number is 77-99-6, formula C6H14O3, molecular weight approximately 134.2 g/mol. These identifiers should match the CoA supplied with each lot.

How is trimethylolpropane supplied in bulk and what is the cost?

TMP is typically supplied as a solid flake or molten/liquid polyol intermediate in bags, drums, or bulk depending on grade. Pricing depends on volume, packaging, and lead time, so request a bulk quote from RawSource rather than relying on spot-price listings.

Disclaimer. Information on this page — including properties, identifiers, hazard, transport (DOT/UN) and tariff (HS) classifications, and applications — is provided for general reference and is compiled from authoritative public sources (e.g. PubChem/ECHA, 49 CFR 172.101, the Harmonized Tariff Schedule). Values are typical and are not a guaranteed specification; the Certificate of Analysis (CoA) for the lot purchased governs. Products are sold for industrial and professional use only. Nothing here is a medical, health, or efficacy claim or advice. Always consult the current Safety Data Sheet (SDS) before handling, storage, transport or disposal, and confirm regulatory status, classification and suitability for your application and jurisdiction. Hazard, transport and tariff classifications must be verified for your specific shipment. RawSource makes no warranty, express or implied, and assumes no liability for use of this information. Trademarks. Third-party trademarks and brand names are the property of their respective owners; any reference is nominative — used only to identify a comparable product — and does not imply affiliation with, sponsorship by, or endorsement by the trademark owner.